{VERSION 6 0 "IBM INTEL NT" "6.0" } {USTYLETAB {CSTYLE "Maple Input" -1 0 "Courier" 0 1 255 0 0 1 0 1 0 0 1 0 0 0 0 1 }{CSTYLE "2D Math" -1 2 "Times" 0 1 0 0 0 0 0 0 2 0 0 0 0 0 0 1 }{CSTYLE "2D Output" 2 20 "" 0 1 0 0 255 1 0 0 0 0 0 0 0 0 0 1 } {CSTYLE "" -1 256 "" 0 1 0 0 255 1 0 0 0 0 0 0 0 0 0 0 }{PSTYLE "Norma l" -1 0 1 {CSTYLE "" -1 -1 "Times New Roman CE" 1 12 0 0 0 1 2 2 2 2 2 2 1 1 1 1 }1 1 0 0 0 0 1 0 1 0 2 2 0 1 }{PSTYLE "Heading 1" -1 3 1 {CSTYLE "" -1 -1 "Times New Roman CE" 1 18 0 0 0 1 2 1 2 2 2 2 1 1 1 1 }1 1 0 0 8 4 1 0 1 0 2 2 0 1 }{PSTYLE "Heading 2" -1 4 1 {CSTYLE "" -1 -1 "Times New Roman CE" 1 14 0 0 0 1 2 1 2 2 2 2 1 1 1 1 }1 1 0 0 8 2 1 0 1 0 2 2 0 1 }{PSTYLE "Maple Output" -1 11 1 {CSTYLE "" -1 -1 " Times New Roman CE" 1 12 0 0 0 1 2 2 2 2 2 2 1 1 1 1 }3 3 0 0 0 0 1 0 1 0 2 2 0 1 }{PSTYLE "Heading 1" -1 256 1 {CSTYLE "" -1 -1 "Times New \+ Roman CE" 1 18 0 0 0 1 2 1 2 2 2 2 1 1 1 1 }3 1 0 0 8 4 1 0 1 0 2 2 0 1 }} {SECT 0 {EXCHG {PARA 256 "" 0 "" {TEXT 256 9 "FCH - B04" }}}{SECT 1 {PARA 3 "" 0 "" {TEXT -1 17 "P\370evodov\341 \350\355sla I" }}{PARA 0 "" 0 "" {TEXT -1 461 "P\370i teplot\354 26,2 \260C byl Hittorf\371v p \370\355stroj s inertn\355mi elektrodami napln\354n roztokem, kter\375 obsahoval 0,065 mol KOH v 1 dm^3 roztoku. B\354hem elektrol\375zy, kt er\341 trvala 42 minut, se hmotnost katody s\351riov\354 zapojen\351ho coulometru na m\354\357 zv\354t\232ila o 80,4 mg (MCu = 63,54 g/mol). Po skon\350en\355 pokusu m\354l katodov\375 roztok objem 69 cm^3 a je ho anal\375zou byla zji\232t\354na koncentrace KOH 0,072 mol/dm^3. Vyp o\350\355tejte p\370evodov\341 \350\355sla iont\371 K(+) a OH(-). \n[t - = 0,191, t- = 0,809]" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "r estart;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 12 "Vstupn\355 data" }} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 59 "c0:=0.065; c:=0.072; V:=69e- 3; mCu:=80.4e-6; MCu:=63.54e-3;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%# c0G$\"#l!\"$" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"cG$\"#s!\"$" }} {PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"VG$\"#p!\"$" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%$mCuG$\"$/)!\"(" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>% $MCuG$\"%aj!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}} {SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330e\232en\355" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 " > " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> \+ " 0 "" {MPLTEXT 1 0 0 "" }}}}}{SECT 1 {PARA 3 "" 0 "" {TEXT -1 18 "P \370evodov\341 \350\355sla II" }}{PARA 0 "" 0 "" {TEXT -1 576 "Roztok \+ HCl o koncentraci 0,05 mol/dm^3 byl elektrolyzov\341n mezi inertn\355m i elektrodami. V okam\236iku, kdy roztokem pro\232el n\341boj 413,9 C, byla elektrol\375za zastavena. Katodov\375 i anodov\375 roztok byly t itrov\341ny roztokem NaOH o koncentraci 0,085 mol/dm^3. Katodov\375 ro ztok v\341\236il 57 g a na jeho neutralizaci bylo spot\370ebov\341no 2 4,8 cm^3 roztoku NaOH. Vypo\350\355tejte p\370evodov\341 \350\355sla o bou iont\371 a objem roztoku NaOH, kter\375 byl zapot\370eb\355 na tit raci 86,5 g anodov\351ho roztoku. Hustota katodov\351ho i anodov\351ho roztoku je 1,006 g/cm^3. [ne = 4,29 mmol, t+ = 0,169, t- = 0,831, \+ V(NaOH) = 8,64 cm^3]" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "resta rt;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 12 "Vstupn\355 data" }} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 85 "c0:=0.05e3; Q:=413.9; cNa:=0 .085e3; mk:=57e-3; VNak:=24.8E-6; ma:=86.5e-3; rho:=1006;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%#c0G$\"\"&\"\"\"" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"QG$\"%RT!\"\"" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>% $cNaG$\"#&)\"\"!" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%#mkG$\"#d!\"$" } }{PARA 11 "" 1 "" {XPPMATH 20 "6#>%%VNakG$\"$[#!\"(" }}{PARA 11 "" 1 " " {XPPMATH 20 "6#>%#maG$\"$l)!\"%" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#> %$rhoG\"%15" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 9 "F:=96485;" }} {PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"FG\"&&['*" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330e \232en\355" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}} }{SECT 1 {PARA 3 "" 0 "" {TEXT -1 48 "Konduktivita a mol\341rn\355 vod ivost z m\354rn\351ho odporu" }}{PARA 0 "" 0 "" {TEXT -1 163 "Ur\350et e mol\341rn\355 vodivosti roztok\371 p\354ti anorganick\375ch slou\350 enin o koncentraci 0,02 mol/dm^3, jejich\236 konduktivita byla zji\232 \235ov\341na m\354\370en\355m odporu vodivostn\355 n\341dobky, " }} {PARA 0 "" 0 "" {TEXT -1 298 "napln\354n\351 m\354\370en\375m roztokem : R(KCl) = 470 Ohm, R(HCl) = 160 Ohm, R(CaCl2) = 304 Ohm, R(K4[Fe(CN)6 ]) = 120 Ohm.\nN\341dobka byla kalibrov\341na pomoc\355 0,02 mol\341rn \355ho roztoku KCl (kappa= 0,2765 S/m).\n(lambda(HCl) = 0,04061 S m^2/ mol, lambda(CaCl2) = 0,02137 S m^2/mol, lambda(K4[Fe(CN)6]) = 0,05415 \+ S m^2/mol." }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "restart;" }}} {SECT 1 {PARA 4 "" 0 "" {TEXT -1 12 "Vstupn\355 data" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 68 "R[KCl]:=470; R[HCl]:=160; R[CaCl2]:=304; \+ R[K4FeCN6]:=120; c:=0.02e3;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>&%\"RG 6#%$KClG\"$q%" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>&%\"RG6#%$HClG\"$g\" " }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>&%\"RG6#%&CaCl2G\"$/$" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>&%\"RG6#%(K4FeCN6G\"$?\"" }}{PARA 11 "" 1 " " {XPPMATH 20 "6#>%\"cG$\"\"#\"\"\"" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 19 "kappa[KCl]:=0.2765;" }}{PARA 11 "" 1 "" {XPPMATH 20 " 6#>&%&kappaG6#%$KClG$\"%lF!\"%" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330e\232en\355" }} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}} }{SECT 1 {PARA 3 "" 0 "" {TEXT -1 25 "Limitn\355 mol\341rn\355 vodivos ti" }}{PARA 0 "" 0 "" {TEXT -1 394 "Limitn\355 mol\341rn\355 vodivost \+ kyseliny m\341seln\351 m\341 p\370i teplot\354 25 \260C hodnotu 3,823e -2 S.m^2/mol, limitn\355 mol\341rn\355 vodivost vod\355kov\351ho katio ntu je 0,03497 S.m^2/mol. Za p\370edpokladu, \236e st\370edn\355 aktiv itn\355 koeficient je roven jedn\351, vypo\350\355tejte limitn\355 mol \341rn\355 vodivost aniontu CH3(CH2)2COO- a p\370evodov\341 \350\355sl a iont\371 p\370i nekone\350n\351m z\370ed\354n\355.\n[lambda(C3H7COO- ) = 0,00326 S.m^2/mol, tK = 0,9147, tA = 0,0853]" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "restart;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 5 "Data " }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 37 "lambdaHA:=3.823e -2; lambdaH:=0.03497;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lambdaHAG$ \"%BQ!\"&" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%(lambdaHG$\"%(\\$!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330e\232en\355" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}}{SECT 1 {PARA 3 "" 0 " " {TEXT -1 43 "V\375po\350et sou\350inu rozpustnosti z konduktivity" } }{PARA 0 "" 0 "" {TEXT -1 540 "Nasycen\375 roztoku jodidu olovnat\351h o m\341 p\370i teplot\354 25 \260C konduktivitu 3,82E-2 S/m, konduktiv ita pou\236it\351 vody je 1,8E-4 S/m. Limitn\355 mol\341rn\355 vodivos ti maj\355 hodnoty\nlambda(Pb(2+)) = 0,0139 S m^2/mol, lambda(I(-)) = \+ 0,00769 S m^2/mol. V\375po\350et prove\357te jednak za p\370edpokladu \+ ide\341ln\355ho roztoku a jednak s odhadem aktivitn\355ch koeficient \371 pomoc\355 Debyeova-H\374ckelova z\341kona. Konstanta Debyeova-H \374ckelova zakona je A=1.176 dm^1.5 mol^-0.5 [c = 0,0013 mol /dm^3, i de\341ln\355 roztok: K(PbI2) = 8,76E-9, re\341ln\375 roztok: gamma = 0 ,8639 K(PbI2) = 5,65E-9]" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "restart;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 12 "Vstupn\355 data " }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 76 "kappa_roz:=3.82E-2; kapp a_H2O:=1.8E-4; lambda_Pb:=0.0139; lambda_I:=0.00769;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%*kappa_rozG$\"$#Q!\"%" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%*kappa_H2OG$\"#=!\"&" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%*lambda_PbG$\"$R\"!\"%" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lamb da_IG$\"$p(!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 17 "A:=1.176 ; cst:=1;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"AG$\"%w6!\"$" }} {PARA 11 "" 1 "" {XPPMATH 20 "6#>%$cstG\"\"\"" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 11 "Koncen trace" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 " > " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 " " 0 "" {TEXT -1 14 "Ide\341ln\355 roztok" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}} {SECT 1 {PARA 4 "" 0 "" {TEXT -1 13 "Re\341ln\375 roztok" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}}{SECT 1 {PARA 3 "" 0 " " {TEXT -1 43 "V\375po\350et konduktivity z disocia\350n\355 konstanty " }}{PARA 0 "" 0 "" {TEXT -1 268 "Vypo\350\355tejte konduktivitu 0,000 2 mol\341rn\355ho roztoku kyseliny propionov\351, jej\355\236 disocia \350n\355 konstanta m\341 hodnotu 1,33E-5 (standardn\355 stav c\260 = \+ 1 mol dm-3). Dal\232\355 pot\370ebn\351 \372daje vyhledejte v tabulk \341ch. Aktivitn\355 koeficienty pova\236ujte za rovny jedn\351. [kapp a = 1,748E-3 S/m]" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "restart ;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 12 "Vstupn\355 data" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 22 "c:=0.0002; K:=1.33E-5;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"cG$\"\"#!\"%" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"KG$\"$L\"!\"(" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 36 " lamda_H:=0.03497; lambda_A:=0.00358;" }}{PARA 11 "" 1 "" {XPPMATH 20 " 6#>%(lamda_HG$\"%(\\$!\"&" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lambda _AG$\"$e$!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}} {SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330e\232en\355" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 " > " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> \+ " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 " " }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> \+ " 0 "" {MPLTEXT 1 0 0 "" }}}}}{SECT 1 {PARA 3 "" 0 "" {TEXT -1 66 "Aci dobazick\341 titrace s konduktometrickou indikac\355 bodu ekvivalence " }}{PARA 0 "" 0 "" {TEXT -1 136 "Roztok kyseliny chlorovod\355kov\351 o objemu 0,1 l a koncentraci 0,01 mol/l byl titrov\341n roztokem hyd roxidu sodn\351ho o koncentaci 0,05 mol/l." }}{PARA 0 "" 0 "" {TEXT -1 73 "Jak z\341vis\355 konduktivita roztoku na mno\236stv\355 p\370id an\351ho titra\350n\355ho \350inidla." }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "restart;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 12 "Vstu pn\355 data" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 28 "c0:=0.01; V:= 0.1; cNa:=0.05;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%#c0G$\"\"\"!\"#" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"VG$\"\"\"!\"\"" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%$cNaG$\"\"&!\"#" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 74 "lambdaH:=0.03497; lambdaOH:=0.01976; lambdaCl:=0.0076 3; lambdaNa:=0.00501;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%(lambdaHG$ \"%(\\$!\"&" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lambdaOHG$\"%w>!\"& " }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lambdaClG$\"$j(!\"&" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lambdaNaG$\"$,&!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330 e\232en\355" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}}{SECT 1 {PARA 3 "" 0 " " {TEXT -1 47 "V\375po\350et disocia\350n\355 konstanty rozpu\232t\354 n\351ho plynu" }}{PARA 0 "" 0 "" {TEXT -1 382 "V 1 dm3 vody o kondukti vit\354 5,32e-4 S/m bylo za teploty 25 \260C a tlaku 101 kPa rozpu\232 t\354no 200 cm^3 amoniaku. Za uveden\375ch podm\355nek je mo\236no p \370edpokl\341dat ide\341ln\355 chov\341n\355 plynn\351ho amoniaku. Vz nikl\375 roztok m\354l konduktivitu 1,079e-2 S/m. Vypo\350\355tejte di socia\350n\355 konstantu amoniaku (aktivitn\355 koeficienty pova\236uj te za jednotkov\351). Dal\232\355 pot\370ebn\351 \372daje vyhledejte v tabulk\341ch.\n[K = 1,84e-5]" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 8 "restart;" }}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 4 "Data" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 76 "V:=1e-3; kappa_v:=5.32e-4; Vg:=200e -6; p:=101e3; T:=298.15; kappa:=1.079e-2;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"VG$\"\"\"!\"$" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>% (kappa_vG$\"$K&!\"'" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%#VgG$\"$+#!\" '" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"pG$\"$,\"\"\"$" }}{PARA 11 " " 1 "" {XPPMATH 20 "6#>%\"TG$\"&:)H!\"#" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%&kappaG$\"%z5!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 9 "R:=8.314;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%\"RG$\"%9$)!\"$" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 38 "lambdaNH4:=0.00737; lambdaOH :=0.01976;" }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%*lambdaNH4G$\"$P(!\"& " }}{PARA 11 "" 1 "" {XPPMATH 20 "6#>%)lambdaOHG$\"%w>!\"&" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}}{SECT 1 {PARA 4 "" 0 "" {TEXT -1 6 "\330e\232en\355" }}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }} }{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}} {EXCHG {PARA 0 "> " 0 "" {MPLTEXT 1 0 0 "" }}}{EXCHG {PARA 0 "> " 0 " " {MPLTEXT 1 0 0 "" }}}}}}{MARK "8" 0 }{VIEWOPTS 1 1 0 1 1 1803 1 1 1 1 }{PAGENUMBERS 0 1 2 33 1 1 }